How we measure the chemical composition of Earth materials

San Diego, CA – If you’ve been following our adventures, you know that we’ve started a project on Black Mountain with our collaborators at the University of San Diego. We’ve dedicated a significant portion of our time in California to sample preparation, and today we see the results of all of our hard work.

In order to address our research questions, we need to understand the compositions of the minerals, rocks, and soils that are present at the field site. To analyze mineral compositions, we are using a scanning electron microscope equipped with an energy-dispersive detector (SEM-EDS). The electron beam interacts with a polished rock specimen to produce characteristic X-rays. The detector separates those X-rays by energy, correlates the energy to specific elements, and maps the distribution of elements in the sample. This technique allows us to determine the compositions of individual minerals in our rocks.

Elizabeth Johnston (USD graduate student) and Dr. Beth O'Shea (USD) are examining mineral compositions using an SEM-EDS.

Elizabeth Johnston (USD graduate student) and Dr. Beth O’Shea (USD) are examining mineral compositions using an SEM-EDS.

Dr. Beth O'Shea (USD) and Amineh AlBashaireh ('18) examine soil samples and discuss analytical strategies.

Dr. O’Shea and Amineh AlBashaireh (’18) examine soil samples and discuss analytical strategies.

To analyze the bulk compositions of our soil samples, we’re using a benchtop X-ray fluorescence spectrometer (XRF). The XRF uses an X-ray beam to generate X-rays from the samples. The generated X-rays are characteristic of specific elements, which the XRF measures and compares to a calibration curve to calculate a concentration. This XRF model is equipped with several modes for analyzing soil or ore samples and allows us to analyze bulk compositions without destroying the sample.

Amineh is analyzing her soil samples with the benchtop XRF. She will use these data to guide her analytical work when we return to Wooster.

Amineh is analyzing her soil samples with the benchtop XRF. She will use these data to guide her analytical work when we return to Wooster.

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Construction of the new Life Sciences building begins, and the geologists welcome our new biologist labmates

Mateer May 2016Wooster, Ohio — The College of Wooster community will soon say goodbye to Mateer Hall (above), which has housed the Biology Department for decades. It will be demolished next month to make way for the new Ruth Williams Hall of Life Science. I haven’t heard anyone yet say they will miss the creaky and undersized Mateer. The new Life Sciences building, which will be joined to the existing Severance Hall (chemistry), will be beautiful, spacious, and filled with the finest of scientific equipment and facilities.

Scovel 216 052416In the meantime the biologists (sensu lato, including neurobiologists, biochemists and so on) have to go somewhere with all their stuff for two years. Scovel Hall will be home for some of the biology labs, so the geologists have been making room throughout the building. I thought I’d record the process at its most chaotic in Scovel 216 (above) and Scovel 219 (below). The biologists have to move everything out of Mateer in just a few days, so our lab tables and just about every other flat surface in Scovel is occupied by specimens, equipment, and massive bottles of distilled water. I especially like the stuffed animals (including a small bear), the crocodile skulls, and the human skeleton in an ancient tall display cabinet.

Scovel 219 052416We are looking forward to spending quality time with our biologist friends. We’re each going to learn a great deal about how the other group works, and we’ll have new appreciation for our disciplines. Science marches forward!

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Thinking like a scientist

San Diego, CA – Thinking like a scientist is a challenging and important learning goal for the Wooster Geologists, and one of the primary reasons that we engage our students in undergraduate research. Although science is often portrayed as a collection of facts or as a series of exercises designed to prove something that is already known, our research students learn that science is a way of thinking. It is a method of inquiry that involves creativity, examining a question from multiple perspectives, and understanding uncertainty. Science requires hypotheses that are testable, data that can be collected and interpreted, and explanations that are supported by evidence. Today, our Black Mountain research group focused on these aspects of science as we developed our research goals and plans for the rest of the summer.

Amineh AlBashaireh ('18) filled the whiteboard with an impressive set of ideas and questions, which jump-started our research discussion.

Amineh AlBashaireh (’18) filled the whiteboard with an impressive set of ideas and questions to prompt our research discussion. On the left are “broad impacts” that define the significance of the research and put the research into context of the larger society. On the right are sources of “potential error,” which Amineh is recognizing and attempting to minimize.

Eventually, we developed a couple of research questions that Amineh will be able to address this summer. We formulated hypotheses for the answers to these questions and designed a research strategy that will generate the data necessary for testing our hypotheses. In the end, we created a research plan that is both achievable (given the constraints of time, expertise, resources, etc.) and flexible enough to allow the research to evolve as Amineh discovers new findings and develops new questions.

For an excellent resource on the process of science, check out the Visionlearning module by Anthony Carpi and Anne Egger. It’s an incredible resource for teachers and students alike.

References:

Carpi, A., and Egger, A.E. 2009. The process of science. Visionlearning POS-2 (8).

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Geochemists know preparation is key

San Diego, CA – While the University of San Diego celebrated their commencement, we commenced lab work on the Black Mountain Project. We began by drying and sieving the soil samples that we collected earlier in the week.

Amineh AlBashaireh ('18) is removing her soil samples from the drying oven.

Amineh AlBashaireh (’18) is removing her soil samples from the drying oven.

Her soil samples display variety of colors and compositions.

Her soil samples display variety of colors and compositions.

Dr. Beth O'Shea (USD) and Amineh discuss the Munsell System for classifying the color of soil.

Dr. Beth O’Shea (USD) and Amineh discuss the Munsell System for classifying the color of soil.

While her samples dry, Amineh is helping prepare samples for analysis on the scanning electron microscope (SEM-EDS). Doesn't she look like a happy geochemist?While her samples dry, Amineh is helping prepare samples for analysis on the scanning electron microscope (SEM-EDS). Doesn’t she look like a happy geochemist?

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Field Work on Black Mountain

San Diego, CA – Amineh AlBashaireh (’18) and I are working with USD scientists, Dr. Bethany O’Shea, Elizabeth Johnston, and Eric Cathcart on the geology of Black Mountain in San Diego, CA.

Black Mountain Open Space Park is a popular hiking and mountain biking destination.

Black Mountain Open Space Park is a popular hiking and mountain biking destination.

The Santiago Peak Volcanics are exposed in the park. These rocks are early Cretaceous in age (~110 Ma) and are thought to represent the volcanic arc associated with the Peninsular Range batholith (Herzig and Kimbrough, 2014).

Slightly metamorphosed andesites and basaltic andesites are present as gray to dark gray aphanitic (fine grained) rocks with scattered phenocrysts (crystals) of plagioclase.

Slightly metamorphosed andesites and basaltic andesites are present as gray to dark gray aphanitic (fine grained) rocks with scattered phenocrysts (crystals) of white plagioclase.

There are also volcaniclastic rocks like this tuff breccia that include large clasts of andesites, basaltic andesites, and other fragmental rocks.

There are also volcaniclastic rocks like this tuff breccia that include large clasts of andesites, basaltic andesites, and fragmental volcanic rocks.

Outcrops of lapillistone contain accretionary lapilli, or rounded sphere of volcanic ash, that hint at the more turbulent and explosive nature of this volcano.

Outcrops of lapillistone contain accretionary lapilli, or rounded spheres of volcanic ash, that show evidence of the more turbulent and explosive nature of this volcano.

Hikers and bikers who visit Black Mountain may be less familiar with its volcanic history and more familiar with its mining history. In the 1920s, this area was briefly mined for arsenic. The arsenic was used in pesticides at the time.

Hikers and bikers who visit Black Mountain may be less familiar with its volcanic history and more familiar with its mining history. In the 1920s, this area was briefly mined for arsenic. The arsenic was used in pesticides at the time (Stewart, 1963).

Our research group is exploring one of the abandoned mines.

Our research group is exploring one of the abandoned mines.

In the mine waste, you can see shiny gold specs of aresenopyrite (FeAsS). Arsenopyrite is a sulfide mineral in which some of the sulfur is replaced with arsenic.

Amineh is studying trace element concentrations in the soils on Black Mountain. Here she is collecting samples. In the next few days, and over the course of the summer, we'll show you how she processes these samples in the lab.

Amineh is studying trace element concentrations in the soils on Black Mountain. Here she is collecting samples. In the next few days, and over the course of the summer, we’ll show you how she processes these samples in the lab.

This was a small (~30 cm) rattlesnake that we saw earlier in the day, and we take field safety seriously, so when we heard a rattle coming from the tall grass, we ended our sampling and called it a day.

This was a small (~30 cm) rattlesnake that we saw earlier in the day, and we take field safety seriously, so when we heard a rattle coming from the tall grass, we ended our sampling and called it a day.

It was an exciting, productive, and safe day in the field. More to come in the next few days as we start on our lab work.

References:

Herzig, C.T. and Kimbrough, D.L. 2014. Santiago Peak volcanics: Cretaceous arc volcanism of the western Peninsular Ranges batholith, southern California. GSA Memoirs 211: 345-363.

Stewart, R.M. 1963. Black Mountain Group in Weber, H.F., Geology and mineral resources of San Diego County, California: San Francisco, California Division of Mines and Geology, 49-50.

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Wooster Geologists in San Diego, CA

San Diego, CA – Wooster Geologists don’t waste any time getting to work on their summer research. Amineh AlBashaireh (’18) and I have made our way to the University of San Diego to start on a new research project with our collaborators in the Department of Environmental and Ocean Sciences. Our trip began with a tour of the department’s facilities in the impressive Shiley Center for Science and Technology.

The grand and welcoming entrance to the Shiley Center, which houses USD's science programs.

The grand and welcoming entrance to the Shiley Center, which houses USD’s science programs.

Visitors to the Department of Environmental and Ocean Sciences are greeted with this stunning display of a donated coral collection.

Visitors to the Department of Environmental and Ocean Sciences are greeted with this stunning display of a donated coral collection.

A favorite lunch spot is the Strata Plaza. The plaza was designed to represent the local stratigraphy and includes regional fossils, stones, and shells.

A favorite lunch spot is the Strata Plaza. The plaza was designed to represent the local stratigraphy and includes regional fossils, stones, and shells.

Our tour ended in the lab, where Dr. Bethany O'Shea and her graduate student, Elizabeth Johnston, gave us an overview of their work. Looks like they mean business!

Our tour ended in the lab, where Dr. Bethany O’Shea and her graduate student, Elizabeth Johnston, gave us an overview of their work. Looks like they mean business!

We’re looking forward to a full week of field and lab work. Stay tuned for more posts from sunny San Diego!

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Wooster’s Fossil of the Week: A phyllocarid crustacean from the Middle Cambrian Burgess Shale of British Columbia, Canada

Canadaspis perfecta Burgess Shale 585We are fortunate at Wooster to have a few fossils from the Burgess Shale (Middle Cambrian) collected near Burgess Pass, British Columbia, Canada, including this delicate phyllocarid Canadaspis perfecta (Walcott, 1912). This species is one of the oldest crustaceans, a group that includes barnacles, crabs, lobsters and shrimp. Please note from the start that I did NOT collect it. The Burgess Shale is a UNESCO World Heritage Site, so collecting there is restricted to a very small group of paleontologists who have gone through probably the most strict permitting system anywhere. I had a wonderful visit to the Burgess Shale with my friend Matthew James in 2009, and we followed all the rules. (The photo below is of the Walcott Quarry outcrop.) Our Wooster specimen was in our teaching collection when I arrived. I suspect it was collected in the 1920s or 1930s and probably purchased from a scientific supply house.

walcottquarryMarrellaSuch a dramatic setting, which is perfect for the incredible fossils that have come from this site.

Canadaspis perfecta drawing

Canadaspis perfecta has been thoroughly studied by Derek Briggs, the most prominent of the paleontologists who have studied the Burgess Shale fauna. The above reconstruction of C. perfecta is from his classic 1978 monograph on the species. He had spectacular material to work with, including specimens with limbs and antennae well represented. Our specimen is a bit shabby in comparison! Nevertheless, we can still make out abdominal segments and a bit of the head shield.

Briggs (1978, p. 440) concluded that C. perfecta likely “fed on coarse particles, possibly with the aid of currents set up by the biramous appendages”. This is a similar feeding mode to many of the trilobites who lived alongside.

References:

Briggs, D.E. 1978. The morphology, mode of life, and affinities of Canadaspis perfecta (Crustacea: Phyllocarida), Middle Cambrian, Burgess Shale, British Columbia. Philosophical Transactions of the Royal Society of London. Series B, Biological Sciences 281: 439-487.

Briggs, D.E. 1992. Phylogenetic significance of the Burgess Shale crustacean Canadaspis. Acta Zoologica 73: 293-300.

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Wooster’s Fossil of the Week: A Recent Sponge Boring from South Carolina

1 Coral on bored bivalveWe’re not actually looking at fossils here, but this bivalve-coral-sponge assemblage from the very modern Myrtle Beach in South Carolina is too cool not to share. Jacob Nowell (Wooster ’18) picked it up while on Spring Break this year and donated it to the collections. This is a bit of very worn bivalve shell punctured by clionaid sponge borings and encrusted by a columnar scleractinian coral.

2 Bored bivalve hingeHow do we know the shell remnant is from a bivalve? This is what’s left of the hinge region, the thickest part of the shell. We can tell this is a heterodont bivalve, probably of the common genus Mercenaria. The shell material is calcite.

3 Coral over EntobiaThe coral is aragonitic and exquisitely preserved. It did not make the long tumbling journey the bivalve shell did. At its encrusting base you can see that it partially covers some of the sponge borings, showing that it attached after the sponge was at least partly gone. The round structures on the coral are the corallites, each of which housed a coral polyp. The corallites have radiating vertical septa inside in the classic scleractinian manner.

4 Entobia gallery 041316 585The sponge boring is the star here. This is a side view showing the interconnected galleries and tunnels excavated by a clionaid sponge like Cliona. As a trace fossil this structure would be known as Entobia. It is very common in the fossil record, especially in the Cretaceous and later.

Bronn 041616Entobia was named and described by Heinrich Georg Bronn (1800-1862), a German geologist and paleontologist. He had a doctoral degree from the University of Heidelberg, where he then taught as a professor of natural history until his death. He was a visionary scientist who had some interesting pre-Darwinian ideas about life’s history. He didn’t fully accept “Darwinism” at the end of his life, but he made the first translation of On The Origin of Species into German.

References:

Bromley, R.G. 1970. Borings as trace fossils and Entobia cretacea Portlock, as an example. Geological Journal, Special Issue 3: 49–90.

Bronn, H.G. 1838. Lethaea geognostica: oder, Abbildungen und Beschreibung der für die Gebirgs-Formationen bezeichnendsten. E. Schweizerbart’s Verlagshandlung, Stuttgart.

Tapanila, L. 2006. Devonian Entobia borings from Nevada, with a revision of Topsentopsis. Journal of Paleontology 80: 760–767.

Taylor, P.D. and Wilson, M.A. 2003. Palaeoecology and evolution of marine hard substrate communities. Earth-Science Reviews 62: 1-103.

Wilson, M.A. 2007. Macroborings and the evolution of bioerosion, p. 356-367. In: Miller, W. III (ed.), Trace Fossils: Concepts, Problems, Prospects. Elsevier, Amsterdam, 611 pages.

 

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A Wooster Geologist Visits Spangler Park

Chloe1Editor’s note: The following entry was written by Chloe Wallace (’17), a student in this year’s Sedimentology & Stratigraphy course. One of our writing assignments was to write a blog post about our recent field trip to Spangler Park (also known as Wooster Memorial Park). I told the class that I would publish on this site the best entry, and Chloe won. It was a very close contest, though, with many other excellent entries. All the following words and images are Chloe’s.

Wooster, Ohio— On April 23, 2016, the Sedimentology and Stratigraphy class took a field trip to the local Wooster Memorial Park, also called Spangler Park. The goal was to study three separate outcrops, and then do a little exploring of our own.

The first stop was a short walk from the entrance to the park, specifically at 40.81475° North and 82.02383° West (above).

This outcrop contains rocks from the Logan Formation of the Lower Carboniferous. The rocks were non-laminated and of silt size, so it is made of siltstone. There are signs of a little bit of oxidation. There are also ripples present on some of the rocks, which is evidence of a shallow water environment. There were gray shale clasts within the siltstone, which were most likely deposited by storm events. The fact that some of the beds are thicker than others is more evidence of storm events because more sediment would have been deposited during storms and thinner beds would have built up during times of less activity. The bedding angles vary throughout the outcrop, also known as cross-stratification, which is more evidence that ripples and dunes were present as part of a flow regime at the time of deposition.

Chloe2Burrow fossils, which are a form of trace fossil, were left behind by deposit feeding organisms on some of the rocks. This is more evidence of a shallow, marine environment. Based on all the sedimentary structures and characteristics found at this outcrop, these rocks were deposited on the shallow shelf, below the fair weather wave base and above the storm wave base.

The Logan Formation is made up of five members, but specifically the Byer member is likely exposed here. Layers of fine sandstone and siltstones with shale sometimes inter-bedded characterize the Byer member (Hunt, 2009). Although it isn’t present in the two photos above, another member is usually deposited right below the Byer Member. It is called the Berne Member and it is composed of molasse rock, which is a quartz-rich conglomerate formed when the eroded material from continental collisions gathers in a foreland basin. In this case it is eroded material from the continental collisions that built up the Appalachians. The eroded material was then deposited to the west in the foreland basin that covers Pennsylvania and Ohio.

The second outcrop we reached was at the bottom of a gorge, along Rathburn Run, specifically at 40.81784° N and 82.02946° W. The exposure was composed of laminated grey shale from the Cuyahoga Formation. It marked a formation boundary because Logan Formation sandstone lies directly above it. This means the grey shale is older than the Logan Formation. Similar to the Logan Formation, there are trace fossils of marine burrowing organisms within the shale.

Chloe3In the above picture you can see an East-West trending joint running through the center of the Cuyahoga Formation grey shale caused by tectonic faulting, which is a phenomenon unrelated to the sedimentary structures.

Chloe4Siderite deposits were also found in some sandstone at the Rathburn run outcrop, which form after deposition, a diagenetic property. Siderite forms in anoxic environments where iron is reduced and sulfur is present. The grey shale of the Cuyahoga Formation isn’t porous enough for siderite replacement to take place, but the sandstone is.

The third outcrop was father upstream along on a cut bank, located at 40.81903° N and 82.02953° W.

Chloe5This photo is taken from across Rathburn Run, from the point bar. This outcrop is much younger in age, from the last time Ohio was affected by glaciation. During the Last Glacial Maximum, specifically the Pleistocene, glacial debris flows deposited the bottom section of the outcrop. The sediment is characterized by a fining upwards sequence and has two scales of support. Some areas of the deposit are composed of large grains within a matrix-support due to debris flow. Other areas of the deposit are composed of sandy conglomerate rock that is grain supported. Overall the sediment is poorly sorted and contains glacial erratics within the sediment, including boulders made of gneiss, granite, and some sedimentary rocks.

A channel cut through the original glacial debris flow deposit and was eventually filled in by wind-blown silt, also known as loess. Loess is characteristically different from the glacial deposit at the bottom of the outcrop. Loess breaks in sheets, which causes it to have steep angles. Overall, the history of this outcrop is that approximately 15,000 years ago debris flow events deposited the glacial sediment at the bottom of the outcrop, then a channel cut into the deposit and that channel eventually filled with eolian (wind-blown) silt.

Chloe6After venturing a little on our own, a few other students and myself came across a fourth outcrop that was from the Logan Formation at an elevation above both the Cuyahoga Formation shales and the glacial deposits. There is more evidence of jointing and cross-stratification that can be seen in the picture.

We saw two separate formations from the Lower Carboniferous during the field trip. We also were able to see another type of sedimentary deposit that was glacial and eolian in origin. Spangler Park displays and exposes a variety of sedimentary structures and sedimentary characteristics. The park can be characterized as displaying a coarsening upwards sequence with the Cuyahoga shale at the bottom, followed by the coarser siltstone and sandstone of the Logan Formation. This kind of coarsening upwards is usually evidence of either regression or progradation.

Both the Logan and Cuyahoga Formations are representative of shallow marine environments, as was seen in the evidence found at Spangler. Further research shows that the Cuyahoga Formation was deposited as part of a marine environment where the shoreline was prograding during the Kinderhookian and possibly very early Osagean (Bork and Malcuit, 1979; Matchen and Kammer, 2006). The Logan Formation followed and was deposited within a marine proximal deltaic environment during the Osagean (Hunt, 2009; Matchen and Kammer, 2006). This explains the coarsening upwards sequence and the marine sedimentary structures and fossils seen throughout the field trip.

References:

Bork, K.B., and Malcuit, R., 1979, Paleoenvironments of the Cuyahoga and Logan Formations (Mississippian) of central Ohio: Geological Society of America Bulletin II, v. 90, p. 1782-1838.

Hunt, H., 2009, Paleocommunities and Paleoenvironments of the Logan Formation (Mississippian, Osagean) of northeastern Ohio [Undergraduate thesis]: Wooster, The College of Wooster, 50 p.

Matchen, D.L., and Kammer, T.W., 2006, Incised valley fill interpretation for Mississippian Black Hand Sandstone, Appalachian Basin, USA: Implications for glacial eustasy at Kinderhookian-Osagean (Tn2-Tn3) boundary: Sedimentary Geology, v. 191, 89-113.

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Wooster’s Fossil of the Week: A craniid brachiopod from the Upper Cretaceous of The Netherlands

1 Isocrania costata Sowerby 1823 double 2 smThese striking little brachiopods are gifts from Clive Champion, a generous Englishman with whom I occasionally exchange packets of fossils. In January I received a surprise box with lots of delicious little brachs, including the two shown above. I remember this type well from a field trip I had to the Upper Cretaceous of The Netherlands.
2 Isocrania costata Sowerby 1823 double 1 smHere we see the reverse sides of the shells at the top. These are most likely dorsal valves of Isocrania costata Sowerby, 1823, from the Lichtenberg Horizon, Upper Maastrichtian (Upper Cretaceous) of the ENCI Quarry near Maastricht, The Netherlands. It is possible they are the closely-related species Isocrania sendeni Simon, 2007, but we don’t have enough material to sort this out.
4 Surlyk 1973 fig 2 copyCraniid brachiopods usually live out their lives attached to hard substrates, as with this Ordovician example. This species of Isocrania, however, was only attached to shelly debris on the seafloor for a short time, outgrowing its substrate early and then living free in the chalky sediment. The above reconstruction image is Figure 2 from Surlyk (1973).

Christian Emig (2009) has a bit of folklore about Isocrania. In medieval Sweden these fossils were called “Brattingsborg pennies” for their size, shape and the face-like image on their interiors. Don’t see the face? Check this out from Emig (2009):
5 Ventral C craniolaris fig 6 SurlykThe “eyes” in this ventral valve are large adductor muscle scars, and the “mouth” and “nose” are a smaller set. Here is one of the “Brattingsborg pennies” legends Emig (2009) relates —

“… at the beginning of the 13th century the archbishop Anders Sunesen spent his last days on the island of Ivö, in his own castle of which the cellar was about 2 km southeast of the castle. In 1221, subjected to the terminal stages of leprosy, he spent his last days on the island. One day he was informed that warriors had stolen a large sum of money from the Brattingsborg castle. They spent that night gambling and carousing in the cellar. The archbishop cursed this money and the following morning the warriors were stunned to find that the coins had turned into stones with a laughing death’s-head on them.”

Thanks for starting us on this trip with your gift, Clive!
3 Isocrania costata Sowerby 1823 sm
References:

Emig, C. 2009. Nummulus brattenburgensis and Crania craniolaris (Brachiopoda, Craniidae). Carnets de Géologie/Notebooks on Geology, Brest, Article, 8.

Hansen, T., and Surlyk, F. 2014. Marine macrofossil communities in the uppermost Maastrichtian chalk of Stevns Klint, Denmark. Palaeogeography, Palaeoclimatology, Palaeoecology 399: 323-344.

Simon, E. 2007. A new Late Maastrichtian species of Isocrania (Brachiopoda, Craniidae) from The Netherlands and Belgium. Bulletin de l’Institut royal des Sciences naturelles de Belgique, Sciences de la Terre 77: 141-157.

Surlyk, F. 1973. Autecology and taxonomy of two Upper Cretaceous craniacean brachiopods. Bulletin of the Geological Society of Denmark 22: 219-242.

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