Minerals in My Toothpaste

WOOSTER, OH – I can’t think of a more exciting thing to do on a Saturday morning than play with minerals and X-rays! Wooster’s Geology Department and the Expanding Your Horizons Program girls explored how minerals are used on a daily basis.  First, we tested the physical properties of minerals and made educated guesses about which minerals are used in common household products, like cleaners and toothpaste. Then we analyzed the products on the new X-ray diffractometer (XRD) to see whether our guesses were correct. Finally, we made our own mineral toothpaste. I don’t think we’ll be going into the toothpaste business any time soon, but the lab now smells minty fresh!

One of the EYH girls prepares a sample of powdered drywall for the XRD.

An EYH student places a prepared sample in the XRD.

After the sample is secured, an EYH student starts the run.

The XRD bombards the sample with X-rays, which diffract at specific angles. Meanwhile, the detector circles the sample and measures the intensity of X-rays at different angles. Each mineral has its own unique spectrum, sort of like an X-ray fingerprint.

Once the girls have their spectrum, they compare their sample to the spectra of known minerals to determine which minerals are in which products.

Mrs. Robertson helps the EYH girls make their own mineral toothpaste. Mmmm!

Melissa Torma ('13) and Ana Wallace ('12) volunteered to help the EYH girls and even had a chance to make their own toothpaste. (Stephanie Jarvis '11 helped, too, but had to lead the EYH girls to their next workshop before I could snap her picture).

The EYH girls search through our collection of polished stones for a souvenir. Thanks for a wonderful time, girls!

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Non-stationarity in climatic response of coastal tree species along the Gulf of Alaska (Senior Independent Study Thesis by Stephanie Jarvis)

The crew in their XtraTufs. From L-R: Stephanie, Deb, Dan, and Greg.

Editor’s note: Senior Independent Study (I.S.) is a year-long program at The College of Wooster in which each student completes a research project and thesis with a faculty mentor.  We particularly enjoy I.S. in the Geology Department because there are so many cool things to do for both the faculty advisor and the student.  We are now posting abstracts of each study as they become available.  The following was written by Stephanie Jarvis, a senior geology and biology double major from Shelbyville, KY.  Here is a link to Stephanie’s final PowerPoint presentation on this project as a movie file (which can be paused at any point). You can see earlier blog posts from her field work by clicking the Alaska tag to the right.

For my IS field work I traveled to Glacier Bay National Park & Preserve, Alaska with my geology advisor, Greg Wiles.  Our field crew also consisted of Deb Prinkey (’01), Dan Lawson (CRREL), and Justin Smith, captain of the RV Capelin.  My focus was on sampling mountain hemlock (Tsuga mertensiana (Bong.) Carrière) at treeline sites to study climate response and forest health using tree ring analysis.  While in Glacier Bay, we also sampled interstadial wood (from forests run over from the glaciers that were now being exposed on the shore) and did some maintenance work on Dan’s climate stations throughout the park.  Back in the lab, Wooster junior Sarah Appleton kept me company and helped me out with some of the tree-ring processing, as did Nick Wiesenberg.

The view from treeline.

An interstadial wood stump, in place. The glacier ran over this tree and buried it in sediment, which is now being washed away.

Site map

I ended up processing cores from only one of the three sites I sampled this summer (the others can be fodder for future projects!).  In addition, I used data from several other sites sampled in previous years.  My data consisted of 3 mountain hemlock sites forming an elevational transect along Beartrack Mountain in Glacier Bay (one described by Alex Trutko ’08), 3 mountain hemlock sites at varying elevations from the mountains around Juneau, AK, and 2 Alaskan yellow-cedar sites (Chamaecyparis nootkatensis (D. Don) Spach) from Glacier Bay used by Colin Mennett (’10).   My purpose was to look into the assumption of stationarity in growth response to climate of trees over time and changing climatic conditions.  According to the Alaska Climate Research Center, this part of AK as warmed 1.8°C over the past 50 years.

Tree-ring base climate reconstructions are important in our understanding of climatic variations and are a main temperature proxy in IPCC’s 2007 report on climate change.  Climate reconstruction is based on the premise that trees at a site are responding to the same environmental variables today that they always have (thus, they are stationary in their response), allowing for the reconstruction of climatic variables using today’s relationship between annual growth and climate.

Greg coring a tree at treeline.

Crossdating using patterns of variations in ring width.

Temperature reconstructions using different proxies, including tree-rings, from the Intergovernmental Panel on Climate Change’s 2007 report.

Recent observations, such as divergence (the uncoupling of long-term trends in temperature and annual growth) and worldwide warming-induced tree mortality, suggest that this assumption of stationarity may not be valid in some cases.  Using mean monthly temperature and precipitation data from Sitka, AK that begin in the 1830s, I compared correlations of annual growth in mountain hemlock to climate at different elevations over time.  My results indicate that mountain hemlocks at low elevations are experiencing a negative change in response to warm temperatures with time, whereas those at high elevations are experiencing a release in growth with warming.  Low-elevation correlation patterns are similar to those of lower-elevation Alaskan yellow-cedar, which is currently in decline due to early loss of protective snowpack with warming.  An increasing positive trend in correlation to April precipitation and mountain hemlock growth indicates that spring snowpack may be playing an increased role in mountain hemlock growth as temperatures warm.  The high elevation mountain hemlock trends suggest the possibility of tree-line advance, though I was not able to determine if regeneration past the current treeline is occurring.  Tree at mid-elevation sites seem to be the least affected by non-stationarity, remaining relatively constant in their growth response throughout the studied time period.  This indicates that reconstructions using mid-elevation sites are likely to be more accurate, as the climatic variable they are sensitive to is not as likely to have changed over time.

Cedar chronologies (green lines) compared to temperature (brown line). Bar graph represents correlation coefficients between annual ring width and temperature, with colors corresponding to labels on the chronologies (orange is lowest elevation PI, blue is higher elevation ER). Asterisks represent significant correlations. Note that the relationship has changed from being positive at ER during the Little Ice Age to negative by the second half of the 20th century.

Mountain hemlock chronologies (green lines) compared to temperature (brown line). The top graph is of the Glacier Bay sites, the bottom is of the Juneau sites. Red represents the low elevation sites, green the mid-elevation, and purple the high elevation. Note that the low elevation sites are decreasing in correlation as the cedars have, while the high elevation sites have experienced a release in growth with warming.

 

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Paleoecological Reconstruction of the Menuha Formation (Upper Cretaceous, Santonian), Makhtesh Ramon Region, Southern Israel (Senior Independent Study Thesis by Andrew Retzler)

A typical Menuha Formation outcrop south of the Makhtesh Ramon structure.

Editor’s note: Senior Independent Study (I.S.) is a year-long program at The College of Wooster in which each student completes a research project and thesis with a faculty mentor.  We particularly enjoy I.S. in the Geology Department because there are so many cool things to do for both the faculty advisor and the student.  We are now posting abstracts of each study as they become available.  The following was written by Andrew Retzler, a senior geology major from Wooster, Ohio.  Here is a link to Andrew’s final PowerPoint presentation on this project as a movie file (which can be paused at any point). You can see earlier blog posts from his field work by clicking the Israel tag to the right. Andrew also created a Wikipedia page on the Menuha Formation.

It all began with an 11-hour flight from NYC to Tel Aviv, Israel with Dr. Wilson and fellow geology senior Micah Risacher. The airport process required for international travel of this sort was an adventure in itself. Thorough baggage checks, stern looks from security personnel, and a bombardment of questions dealing with our reasons for travelling were all offset by a seemingly endless and free movie selection on the flight! Eventually, we reached our arid destination of Mitzpe Ramon, the city that would serve as our basecamp for the next two weeks.

One of the reasons behind our trip was to scour the Menuha Formation outcrops throughout the Makhtesh Ramon region (shown above). We were hoping to collect and analyze various fossils in order to reconstruct an environment that once flourished during the Cretaceous. This process also involved taking detailed measurements and notes on each outcrop to create stratigraphic columns of each locality. This would become the basis of my thesis. Of course, none of this could have been possible without the help of our all-knowing field guide, Yoav Avni, and our shark specialist, Stuart Chubb, from the Birkbeck College of London.

Although my thesis has a strong focus on the shark and other fish teeth collected from the Menuha Formation, it also incorporates oysters, trace fossils, and several benthic/planktic foraminiferans. At least ten different species were represented in the isolated teeth: Cretalamna appendiculata, Cretoxyrhina mantelli, Squalicorax falcatus?, Squalicorax kaupi, Scapanorhynchus rapax, Scapanorhynchus raphiodon?, Carcharias samhammeri, Carcharias holmdelensis, and two other fish (Hadrodus priscus and Micropycnodon kansasensis?). Many of these fish were thought to occupy outer shallow marine realms, where the continental shelf begins transitioning into the slope. A few of the sharks are also known for being top Cretaceous predators, four or more meters in length, whose diets included plesiosaurs, mosasaurs, and ichthyodectids.

Cretalamna appendiculata tooth, a shark often considered to be an ecological generalist.

Scapanorhynchus rapax tooth. Related to the extant Goblin Shark, S. rapax had the ability to protrude its mouth in order to capture prey.

Cretoxyrhina mantelli tooth. Considered a superpredator of the Cretaceous seas, this shark could reach 5-6 meters in size.

Squalicorax kaupi tooth. The Squalicorax genus is the only group to exhibit serrated dentition, like so, in the Late Cretaceous.

Hadrodus priscus pharyngeal teeth. These teeth would have been found near the back of the throat arranged in a comb-like structure to help crush exoskeletons.

LEFT: The extended left valve of a Pycnodonte vesicularis. RIGHT: Planktic, biserial foraminiferan test (possibly Heterohelix sp.) that has been replaced by silica.

The Menuha Formation consists mainly of white and yellow/brown, glauconitic chalks that were often marly or conglomeratic. This chalk comprised a variety of phosphatic peloids, microteeth, irregular echinoid spines, and benthic/planktic foraminiferans that clearly represent a shallow marine environment.

Irregular echinoid spine recovered from the partially dissolved Menuha chalk.

Microtooth from the Menuha chalk.

Correlating the paleontology with their lithological context, a shallow marine outer continental shelf/middle continental slope environment is suggested as the paleoenvironment of the Menuha Formation. This environment would have also flourished with a variety of small to medium-sized fish, squid, and larger vertebrates (plesiosaurs and mosasaurs) in order to sustain such a shark population. Unlike the deep environment that has often been suggested, my thesis provides strong evidence towards a shallow marine environment during the early formation of the Makhtesh Ramon structure. My work also marks the first identification of the fish teeth within the Menuha Formation, beginning my contributions to the scientific world.

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A Paleoenvironmental Analysis of the Zichor Formation in the Cretaceous of Southern Israel (Senior Independent Study Thesis by Micah Risacher)

Editor’s note: Senior Independent Study (I.S.) is a year-long program at The College of Wooster in which each student completes a research project and thesis with a faculty mentor.  We particularly enjoy I.S. in the Geology Department because there are so many cool things to do for both the faculty advisor and the student.  We are now posting abstracts of each study as they become available.  The following was written by Micah Risacher, a senior geology major from Columbus, Ohio.  Here is a link to Micah’s final PowerPoint presentation on this project as a movie file (which can be paused at any point). You can see earlier blog posts from Micah’s field work by clicking the Israel tag to the right.

In the summer of 2011 Wooster geologists Mark Wilson, Andrew Retzler, and I went to the Negev Desert in southern Israel.  We were met by a colleague from England, Stewart Chubb as well as our guide and host Yoav Avni of the Geological Survey of Israel.  The small town of Mitzpe Ramon on the edge of the Makhtesh Ramon (Figure 1) would serve as our home for the next two weeks as we explored the Ramon structure.

Figure 1. A look into the Makhtesh Ramon structure.

My research includes the Zichor Formation which can be found throughout the Makhtesh Ramon structure.  However I focused on three separate locations known as the northern, southern, and western locations.  Each location had different features exposed, the southern location (Figure 2) exposed the Zichor very well, yet it was quite hard to get at it.

Figure 2. Southern section with the Zichor section labeled.

The purpose of my I.S. was to determine the paleoenvironment of this particular formation (Zichor) using the paleontology, sedimentology, and stratigraphy seen in the field/lab.  I found many well preserved echinoids (not destroyed by churning waters), Thalassinoides trace fossils, high mud content and shell fragments in the lithology, as well as several minor regression/transgression cycles.  All of these point to a primarily shallow marine environment that would slightly deepen once or twice before shallowing again.

The echinoids (Figure 3) found were so well preserved that they could be identified down to the species level and greatly helped to correlate this assemblage with others like it around the world during that time.  This process both helps to verify my results as well as put my sites in perspective with similar ones around the world.  Hopefully, this study will go a ways into settling the current dispute as to whether or not this region was a shallow or deep sea environment during the Late Cretaceous.

Figure 3. The most prevalent echinoids Hemiaster batnensis and Rachiosoma delamarri respectively; scale bars=1cm.

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Wooster’s Fossil of the Week: Reef-forming brachiopods (Middle Permian of southwestern Texas)

In my early days of teaching paleontology I had an enthusiastic trading program with colleagues around the country. I would supply fine fossils from the Upper Ordovician of southern Ohio for what I considered exotic specimens from elsewhere. In one of the trades I received a block of limestone from the Road Canyon Formation found in the Glass Mountains of southwestern Texas. It was from the Roadian Stage of the Guadalupian Series of the Permian System, so about 270 million years old.

This limestone is famous for its silicified fossils. The original calcite shells of the fossils were replaced by silica (similar to the mineral quartz), yet the matrix of the limestone remained mostly calcite. This meant that my students and I could immerse the limestone block in hydrochloric acid and watch the calcite matrix dissolve and the silicified shells remain as an insoluble residue. What emerged from the acid were beautiful fossils where even the finest spines are preserved.

Cluster of Hercosestria cribrosa brachiopods with the conical ventral valve (VV) and lid-like dorsal valve (DV) labelled.

Our particular block was part of a reef complex in which the primary framework was made by conical brachiopods attached to each other by long spines. These brachiopods are unlike any that came before or since. Each shell consists of two valves: the ventral valve is an open cone and the dorsal valve attaches to it as a hinged lid. The spines come from the ventral valve and wrap around other shells to make a wave-resistant structure — a reef. These brachiopod reefs were unique to the Permian.

The species we have, Hercosestria cribrosa Cooper & Grant 1969, belongs to the Superfamily Richthofenioidea in the Order Productida, so they are often called richthofenids and productids. Hercosestria had its moment of paleontological fame in the mid-1970s. Two prominent paleontologists, Richard Cowen and Richard Grant, debated the role of models in assessing the functional morphology of extinct species.  Richthofenid brachiopods were used as an example: did they flap their dorsal valves to create a current (Cowen’s suggestion), or did they crack the valves open and pump the water in and out with their fleshy lophophores? Grant showed a specimen of Hercosestria cribrosa with another brachiopod living on its dorsal valve, convincingly demonstrating that the valves did not likely flap.

On the left is a figure from Grant (1975) showing Hercosestria cribrosa with a small brachiopod living on its dorsal valve; on the right is a side view of two H. cribrosa ventral valves with attaching spines.

To make it even more interesting, by the 1980s there was considerable support for the idea that richthofenid brachiopods like Hercosestria had algal symbionts in their tissues and thus were effectively photosynthetic!

Reconstruction of a Permian reef from the University of Michigan Exhibit Museum of Natural History.

To see the other Wooster’s Fossil of the Week posts, please click on this link or the appropriate tag to the right.

References —

Cooper, G.A. and Grant, R.E. 1969. New Permian brachiopods from west Texas. Smithsonian Contributions to Paleobiology 1: 1-20.

Cowen, R. 1975. ‘Flapping valves’ in brachiopods. Lethaia 8: 23-29.

Cowen, R. 1983, Algal symbiosis and its recognition in the fossil record: in Tevesz, M.J.S. and McCall, P.L., eds., Biotic Interactions in Recent and Fossil Benthic Communities: Plenum Press, New York, p. 431-478.

Grant, R.E. 1975. Methods and conclusions in functional analysis: a reply. Lethaia 8: 31–33.

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Bioerosion on oysters across the Cretaceous-Paleogene Boundary in Alabama and Mississippi (USA) (Senior Independent Study Thesis by Megan Innis)

This is my research team at a road-cut locality in Mississippi. (Photo courtesy of George Phillips.)

Editor’s note: Senior Independent Study (I.S.) is a year-long program at The College of Wooster in which each student completes a research project and thesis with a faculty mentor.  We particularly enjoy I.S. in the Geology Department because there are so many cool things to do for both the faculty advisor and the student.  We are now posting abstracts of each study as they become available.  The following was written by Megan Innis, a senior geology major from Whitmore Lake, Michigan. You can see earlier blog posts from Megan’s field work by clicking the Alabama and Mississippi tags to the right.

During the summer of 2010, I traveled to Alabama and Mississippi with my research team including Dr. Mark Wilson, Dr. Paul Taylor, and Caroline Sogot.  Our trip was about ten days and included fieldwork and research. The purpose of our research was to collect fossils from below and above the Cretaceous-Paleogene (K/Pg) boundary to try and understand the Cretaceous mass extinction from a microfaunal level.

I chose to focus my thesis on oysters and the sclerobionts associated with these calcareous hard substrates.  Although my study was focused on oysters, I also collected a wide variety of other specimens including nautiloids, ammonites, belemnites, corals, sharks teeth, and bryozoans.

The oyster species present in each system.

When I got back to school in August, I identified all of my oyster species (three total) and began to identify and collect data for the sclerobionts. The oysters from the Cretaceous included Exogyra costata and Pycnodonte convexa and the oysters from the Paleogene included Exogyra costata, Pycnodonte convexa, and Pycnodonte pulaskiensis.

 

 

I identified nine sclerobionts including Entobia borings; Gastrochaenolites borings; Oichnus borings; Talpina borings; serpulids; encrusting oysters; encrusting foraminiferans; Stomatopora bryozoans; and “Berenicia” bryozoans.  My research showed:

1) Bioerosion of oyster hard substrates was common in the Late Cretaceous and Paleogene and sclerobionts were abundant before and after the extinction.

2) Entobia sponge borings appear to increase in abundance across the K/Pg boundary and become more common in the Paleogene.

3) Gastrochaenolites borings, made by bivalves, and serpulids were more prevalent in the Late Cretaceous, suggesting boring bivalves and serpulids were significantly reduced after the extinction.

4) Encrusting oysters and foraminiferans were more common in the Late Cretaceous, but also relatively abundant on Pycnodonte pulaskiensis in the Paleogene.

5) Encrusting bryozoans were more common in the Late Cretaceous and absent in the Paleogene, suggesting bryozoans were severely affected by the extinction.

6) Talpina borings were only found on Pycnodonte pulaskiensis in the Paleogene, but no significant data was collected elsewhere.

To my knowledge, this is the first study of bioerosion on oysters across the K/Pg boundary.

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When Volcanoes Erupt

WOOSTER, OH – Students in the Geology of Natural Hazards course spent a day studying the products of volcanic eruptions. Here are some of the outstanding samples in our volcanic collection:

Reticulite is a delicate network of basaltic glass that forms during Hawaiian fire fountaining. Volatiles expand easily in the low-viscosity magma, creating a dense network of interconnected vesicles separated by thin strands of quenched lava (sideromelane).

Accretionary lapilli are rounded pea-sized pieces of tephra that consist of volcanic ash. Ash aggregates into balls because of electrostatic forces in the eruption column.

Volcanic bombs are formed when lava is ejected and becomes airborne. The fusiform bomb has a rounded aerodynamic shape with an elongated tail, which tells us that the material was molten when it was ejected and was shaped as it traveled through the air.

The glassy surface of this basalt shows the classic ropy texture of pahoehoe. Ropy pahoehoe develops when the surface of a lava flow becomes partially solidified and wrinkles as the underlying lava continues to flow.

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Wooster’s Fossil of the Week: A little brachiopod gets a name (Middle Jurassic of southern Israel)

Moorellina negevensis Krawczyński & Wilson 2011; 1a – general view of the dorsal valve interior; 1b – oblique view showing brachial cavities and cardinalia.

This week our fossil star is a new brachiopod species a Polish colleague (Cezary Krawczyński — a brachiopod expert) and I described in this March 2011 paper:

The first Jurassic thecideide brachiopods from the Middle East: A new species of Moorellina from the Upper Callovian of Hamakhtesh Hagadol, southern Israel. Acta Geologica Polonica, Vol. 61, No. 1, p. 71-77. [Free pdf available on that site.]

These tiny shells of Moorellina negevensis encrust corals and sponges in the Matmor Formation (Lamberti Zone, Upper Callovian, Middle Jurassic) in the Negev Desert of southern Israel.  (Our species name means “from the Negev”.) They are prominent members of a diverse sclerobiont assemblage including tubeworms, oysters, bryozoans and various borings. Several specimens were collected over the past few years of our Wooster work in Israel. Wooster student Will Cary and I will return to these outcrops in Israel this summer for further Jurassic work.

Moorellina negevensis is among the smallest of adult brachiopods, averaging only about two millimeters in width. It is the first species of the Order Thecideida found in the Jurassic of the Middle East. No doubt it escaped previous notice because it is so tiny!

One of our specimens has a gall-like structure that we believe was likely made by a ascothoracid parasite in the shell. The ascothoracids are tiny crustaceans usually found as parasites in echinoderms and cnidarians.

Parasitic (ascothoracid?) infestation in the dorsal valve interior of Moorellina negevensis; A – interior of the dorsal valve of Moorellina negevensis with parasitic (ascothoracid?) infestation marked in red; B – enlargement of parasitic infestation, posterior-lateral view; C – Synagoga paucisetosa Grygier, 1990, a recent ascothoracid parasite (redrawn from Grygier 1990, slightly modified); D – recent ophiuroid Ophiocten sericeum (Forbes, 1852) with the genital bursae infested by Ascothorax ophioctenis Djakonov, 1914 (redrawn from Wagin 1946, slightly modified).

So a little fossil with the surprise of an even smaller fossil inside!

Matmor Formation exposed in the Matmor Hills, Hamakhtesh Hagadol, Negev Desert, southern Israel. Type locality for Moorellina negevensis. This kind of outcrop is heaven for paleontologists and sedimentary geologists. It is a beautiful desert setting.

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Wooster Geologists Celebrate I.S. Monday

WOOSTER, OH – Alumni will fondly recall the tradition of I.S. Monday, our annual celebration of the completion of I.S. Today, seniors celebrate their hard work by donning their commemorative t-shirts and marching in the I.S. parade. We salute you, seniors, and wish you luck on your upcoming oral defenses!

Congratulations to the Wooster Geology Class of 2011 for making it to I.S. Monday! Pictured from left to right: Micah Risacher ('11), Dr. Shelley Judge, Elizabeth Deering ('11), Michael Snader ('11), Megan Innis ('11), Dr. Meagen Pollock, Andrew "the Shark" Retzler ('11), and Becky Alcorn ('11). Members of the class of 2011 not pictured here: Jesse Davenport, Stephanie Jarvis, Sam Spencer, and LaShawna Weeks.

 

 

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Wooster’s Fossil of the Week: A woolly mammoth tooth (Late Pleistocene of Holmes County, Ohio)

Since we had a mastodon tooth as our last Fossil of the Week, paleontological symmetry demands we have a mammoth tooth this week. The fossil above also comes from the productive bogs of Holmes County a few miles south of Wooster.

Our tooth is from a young woolly mammoth (Mammuthus primigenius). These were true elephants, unlike the mastodons which were only distant cousins in another family. You can tell a mammoth tooth from a mastodon tooth by the flat ridges on its chewing surface rather than pointy cusps.

The woolly mammoth had long tusks (one of which we have in a display case outside my office) and, of course, plenty of long hair to keep it warm in the tundra environments it inhabited. They were grazers, apparently digging up grass and other ground vegetation with their tusks.

Mammuthus primigenius appeared about 150,000 years ago during the Pleistocene, and the last individual died surprisingly only 3700 years ago on a small Alaskan island. They are well known from frozen remains in Siberia — and from a new Japanese attempt to clone them from frozen tissue. (I’ve heard that one so many times …)

In June 2008, a Wooster Independent Study team saw cross-sections of mammoth footprints at The Mammoth Site, Hot Springs, South Dakota (see below). They could only be identified as such because of the dozens of mammoth skeletons around them!

Woolly mammoths in northern Spain (from a mural by Mauricio Antón).

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